报告题目：Chiral Sulfoxide Ligands in Asymmetric Reactions

报告时间：7月6日下午3：30

报告地点：化学楼424会议室

廖建，中科院成都生物所研究员。1994年本科毕业于上海交通大学应用化学系， 2002年在中科院成都有机所获理学博士学位。2003年至2006年在美国Penn State University材料系、化学系从事博士后研究。2006年2月回国，在中科院成都有机所开始独立科研工作，任不对称合成与手性技术四川省重点实验室副主任，所学位评定委员会委员。2008年入选中国科学院“西部之光”人才计划，2009年入选四川省学术和技术带头人后备人选。2010年9月调入中科院成都生物所任研究员。2014年任天然药物与临床转化实验室主任。主要从事手性配体设计、不对称催化方法学以及天然产物合成研究。在国际核心学术刊物（包括J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Sci., Org. Lett., Chem. Eur. J.等）上发表学术论文30余篇。

代表性论文：

1. T. Jia, P. Cao*, J. Liao* “Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)” Chem. Sci. 2018, 9, 546.（Review）
2. B. Chen, P. Cao, X. Yin, Y. Liao, L. Jiang, J. Ye, M. Wang, J. Liao* “Modular Synthesis of Enantioenriched 1,1,2-Triarylethanes by an Enantioselective Arylboration and Cross-Coupling Sequence” ACS Catal. 2017, 7, 2425. 
3. L. Jiang, P. Cao*, M. Wang, B. Chen, B. Wang, J. Liao* “Highly Diastereo- and Enantioselective Cu-Catalyzed Borylative Coupling of 1,3-Dienes and Aldimines” Angew. Chem. Int. Ed. 2016, 55, 13854.
4. T. Jia, P. Cao, B. Wang, Y. Lou, X. Yin, M. Wang, J. Liao* “A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes” J. Am. Chem. Soc. 2015, 137, 13760 ( Highlighted by JACS Spots).
5. Y. Lou, P. Cao, T. Jia, Y. Zhang, M. Wang, J. Liao* “Cu-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes” Angew. Chem. Int. Ed. 2015, 54, 12134.
6. D. Wang, P. Cao, B. Wang, T. Jia, Y. Lou, M. Wang, J. Liao* “Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N-Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand” Org. Lett. 2015, 17, 2420. 
7. J. Wang, M. Wang, P. Cao, L. Jiang, G. Chen, J. Liao* “Rh-Catalyzed Asymmetric Arylation of β,γ-Unsaturated α-Ketoamides for the Construction of Nonracemic γ,γ-Diarylcarbonyls” Angew. Chem. Int. Ed. 2014, 53, 6673.
8. L. Du, P. Cao, J. Xing, Y. Lou, L. Jiang, L. Li, J. Liao* “Hydrogen Bond Promoted Palladium-Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands” Angew. Chem. Int. Ed. 2013, 52, 4207.
9. G. Chen, J. Gui, L. Li, J. Liao* “Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in the Rh-Catalyzed Asymmetric Conjugate Additions” Angew. Chem. Int. Ed. 2011, 50, 7681 (hot paper).
10. J. Chen, J. Chen, F. Lang, X. Zhang, L. Cun, J. Zhu, J. Deng, J. Liao* “A C2-Symmetric Chiral Bis-Sulfoxide Ligand in Rhodium-Catalyzed Reaction: Asymmetric 1, 4- Addition of Sodium Tetraarylborates to Chromenones” J. Am. Chem. Soc. 2010, 132，4552.